Our research on temperature swing solvent extraction for hypersaline desalination is accepted for publication in ES&T Letters!
Our research on temperature swing solvent extraction for hypersaline desalination is accepted for publication in ES&T Letters!
May 07, 2019
Our research article on Temperature Swing Solvent Extraction (TSSE) has been accepted for publication in Environmental Science & Technology Letters!
In this study, we demonstrate TSSE that is membrane-less and not based on evaporative phase-change for the desalination of hypersaline brines. The technology utilizes a low-polarity solvent with temperature-dependent water solubility for the selective extraction of water over salt from saline feeds. We show that TSSE can desalinate brines with salinities as high as ≈234,000 ppm total dissolved solids (4.0 M NaCl) and achieve salt removals up to 98.4%. Importantly, only moderate temperatures of <70 °C are needed to drive the separation, which can be supplied by inexpensive or even free low-grade thermal sources for enhanced sustainability. Because TSSE does not require a phase change of water, the penalizing energy cost associated with the enthalpy of vaporization is inventively sidestepped. Lastly, we experimentally demonstrate >50% water recovery in the desalination of 1.5 M NaCl brine, i.e., >50% volume reduction. TSSE showed promising potential for the growing market of high-salinity dewatering/desalination applications.